Document
Densification of nanocrystalline hydroxyapatite powder via sintering: enhancing mechanical properties for biomedical applications
Linked Agent
Title of Periodical
Materials Research Express
Country of Publication
Kingdom of Bahrain
Place Published
Sakhir, Bahrain
Publisher
University of Bahrain
Date Issued
2023
Language
English
Subject
English Abstract
Abstract:
The effect of compaction load, sintering temperature and soaking time on the sinter-ability and
densification of Nano crystalline hydroxyapatite (HA)was assessed. The compaction and sinter-ability
of HA particles was done at three different compaction loads and temperatures ranging from 1 ton to 5
ton and 850 °C to 1250 °C, respectively. Compaction of the green pellets was best achieved at 5-ton
compaction load and it’s percent green densification was up to 50% of the theoretical density of HA
(3.16g cm−3 ). For sintered density, the best results were achieved at a temperature of 1250 °C and a
compaction load of 1 ton which were 98% of the theoretical density. Soaking time at these sintering
temperatures was varied between 1 and 3 h and was found that with the variation of soaking time from
3 h to 1 h, the sintered density decreased tremendously at 850 °C from 85% to 50% whereas at higher
temperatures the decrease in density was only 4 to 6%. The maximum hardness of 625 (±28) HV1 was
obtained for HA sintered at 1250 °C with a soaking time of 3 h. Phase analyses were carried out using
an x-ray diffractometer. The HA phase was stable even at the highest sintering temperature of 1250 °C
and did not decompose into αtri-calcium phosphate (TCP) and β TCP. The grain size was reduced by
decreasing soaking time and lowering sintering temperature.
Member of
Identifier
https://digitalrepository.uob.edu.bh/id/0fc7b7e5-80a5-4a92-8cbf-034415b8f719