Document

Densification of nanocrystalline hydroxyapatite powder via sintering: enhancing mechanical properties for biomedical applications

Author
Linked Agent
Khan, R, Author
Amjad, M, Author
Muhammad, R, Author
Yasir, M, Author
Title of Periodical
Materials Research Express
Country of Publication
Kingdom of Bahrain
Place Published
Sakhir, Bahrain
Publisher
University of Bahrain
Date Issued
2023
Language
English
English Abstract
Abstract: The effect of compaction load, sintering temperature and soaking time on the sinter-ability and densification of Nano crystalline hydroxyapatite (HA)was assessed. The compaction and sinter-ability of HA particles was done at three different compaction loads and temperatures ranging from 1 ton to 5 ton and 850 °C to 1250 °C, respectively. Compaction of the green pellets was best achieved at 5-ton compaction load and it’s percent green densification was up to 50% of the theoretical density of HA (3.16g cm−3 ). For sintered density, the best results were achieved at a temperature of 1250 °C and a compaction load of 1 ton which were 98% of the theoretical density. Soaking time at these sintering temperatures was varied between 1 and 3 h and was found that with the variation of soaking time from 3 h to 1 h, the sintered density decreased tremendously at 850 °C from 85% to 50% whereas at higher temperatures the decrease in density was only 4 to 6%. The maximum hardness of 625 (±28) HV1 was obtained for HA sintered at 1250 °C with a soaking time of 3 h. Phase analyses were carried out using an x-ray diffractometer. The HA phase was stable even at the highest sintering temperature of 1250 °C and did not decompose into αtri-calcium phosphate (TCP) and β TCP. The grain size was reduced by decreasing soaking time and lowering sintering temperature.
Member of
Identifier
https://digitalrepository.uob.edu.bh/id/0fc7b7e5-80a5-4a92-8cbf-034415b8f719